Maintain boiler water Phosphate to avoid caustic gauging 18. Boiler system failure Boiler tube shows effect of acid attack Violent rupture caused by hydrogen embrittlement Acidic condition generated on tube surface beneath the deposits. Presence of chloride was confirmed 19.
Plant Service Bulletin: Boiler Water Phosphate Chemistry
concentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and then return to the original levels on subsequent load
Basic Boiler Principles Water and solids enter the boiler Water leaves the boiler as steam Solids concentrate in the boiler Therefore the boiler water will contain more solids than the feedwater This Concentrating effect is called Phosphate/Polymer Treatment Characteristics
Carryover of boiler water, resulting from inadequate steam-water separation equipment in the boiler, caused this turbine deposit problem. The nature of silica deposits found on turbine blades varies greatly. Table 18-1 lists a number of silica compounds that have been identified in various studies of turbine blade deposition.
used to measure contamination in phosphate-treated boiler water because the phosphate salts are converted to phosphoric acid, which has high conductivity. Figure 3. pH and conductivity of sodium hydroxide solutions. Every point on the line corresponds to a differentconcentration of sodium hydroxide. Figure 4. The principle of cation conductivity.
treated boiler water. The cation column converts sodium hydroxide to water and removes the background conductivity. Cation con-ductivity cannot be used to measure contamination in phosphate-treated boiler water because the phosphate salts are converted to
Using of congruent phosphate as equilibrium phosphate boilers water
Principle of Surface Area Water Multiple Droplet Water Droplets Oxygen Removing Oxygen. 16 Phosphate Polymer Boiler Water Polymers are Cil hCrucial to the Success of any Internal Treatment Programs In a phosphate precipitation treatment program, the Phosphate Treatment Alone Not Optimal
Why is phosphate dosing done in a boiler? - Quora
Hartford Steam Boiler Boiler Water Treatment Phosphate compounds are common additives for boiler water treatment. Phosphate compounds react with any remaining hard water compounds to create a soft sludge that is eliminated through blowdown. Trisodium phosphate is the most common compound for lower pressure boilers. Phosphates also
Mar 25, 2002 · Silicate and phosphate are determined in boiler water at power plants; 60120 samples h −1 be analyzed. Determination ranges are 0.0522 mg l −1 for silicate and 0.124 mg l −1 for phosphate. Relative standard deviations for metasilicate and orthophosphate were ≤1.2 and 1.3%, respectively.
In high pressure boilers, an excess of a soluble phosphate is added to the boiler water to precipitate the residual calcium ions in the form of a non-adherent precipitate of calcium phosphate and thus the scale formation is prevented. 20. Differentiate between drinking water and boiler feed water. S.No Drinking water Boiler feed water
Mar 18, 2015 · Phosphate conditioning Scale formation can be prevented by adding sodium phosphate to the boiler water which reacts with the hardness producing ions and forms easily removable phosphate salts of respective ions 3CaCl2 (Boiler water) + 2 Na3PO4 Ca3(PO4)2 + 6 NaCl ELECTRO DIALYSIS Principle: Electrodialysis is an electrochemical process
reduce the risk of free sodium hydroxide in boilers water, the Na/PO4 ratio of this modified phosphate treatment can vary between 2.4 and 2.8, while also maintaining the alkalinity high enough to minimize corrosion of carbon steel. The concentration of phosphate in boilers water
ULTRAMARINESM HP BWT Program • Drew Marine pioneered the modified phosphate-pH treatment Utilizes disodium orthophosphate and caustic so that no free caustic is generated in the boiler water Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the program Went into effect in the marine industry in the 1960s and has
Accurate chemical water treatment and skillful maintenance are key elements to attain optimal boiler operation. Boiler Water Treatment: Principles and Practice analyzes the fundamentals of the mechanical operation of boilers, together with the applied chemistry required to achieve waterside cleanliness and cost-effective, optimal boiler operation.
Stephen Hall, in Branan's Rules of Thumb for Chemical Engineers (Fifth Edition), 2012. Introduction. Boilers are essentially shell-and-tube heat exchangers, with water being boiled to steam or transformed to high pressure hot water. Heat is generated by burning a fossil fuel; the combustion gas can be ducted around tubes containing the water (water-tube boiler), or the hot gas can pass inside
Mar 23, 2010 · In steamships boiler feed water consists of condensate returns along with make-up feed water. The testing of boiler feed water is imperative to prevent many conditions which are detrimental to safe, efficient boiler steaming. These main culprits are high acid and oxygen content causing corrosion and pitting inside the water tubes and boiler internals.